Carbohydrates are biomolecules composed of carbon, oxygen, and hydrogen. The general formula for carhohydrates is Cn(H2O)n.
|Learning Objectives: Understand carbohydrates and describe the structure of mono-, di-, and poly-saccharides.|
They are commonly known as sugars or sacchrides (Figure 1).
This is what you will learn:
Types of Carbohydrates
Carbohydrates are categorized into four types, viz. monosacchrides, disaccharides, oligosaccharides, and polysaccharides.
Saccharides and their derivatives play key roles in growth, development, fertilization, blood clotting, and immunity. Carbohydrates are stored as glycogen in a cell.
This course covers types, their characteristics, examples, and applications of carbohydrates.
Monosaccharides are the simplest form of carbohydrates and contain three to seven carbon atoms.
They are aldehydes (aldose) or ketones (ketose) with two or more hydroxyl groups.
Monosacchrides cannot be dissociated or hydrolyzed into smaller units.
They show optical activity in that they can rotate light in clockwise direction (D or dextro) or in anticlockwise direction (L or laevo).
These two forms are called isomers and appear as mirror images of each other.
Examples of Monosacchrides
Commonly known monosacchrides are glucose, fructose, galactose, xylose, and ribose.
Glucose (Figure 2) is a major source of energy for a cell. Blood sugar means “glucose in the blood”.
Fructose (Figure 4) is mainly found in vegetables and fruits.
Galactose (Figure 5) is present in milk and dairy products.
Xylose (Figure 5) is a monosaccharide of the aldopentose type consisting of five carbon atoms and is also used as a diagnostic agent to observe malabsorption in veterinary medicine.
Ribose (Figure 6) is a pentose sugar produced by the body. It is used as a medicine.
Glucose and fructose are the most commonly occuring monosaccharides.
Table below shows difference between glucose and fructose.
|The most important monosaccharide is glucose, also known as blood sugar is the main energy source for the body||Also known as fruit sugar and are commonly manufactured in the lab. It is also a source of energy. Often added to food and drinks to improve taste|
|Unlike fructose, insulin is secreted primarily in response to elevated blood concentrations of glucose, and insulin facilitates the entry of glucose into cells||Does not stimulate substantial insulin release|
|Functional group in the structure of glucose is an aldehyde||
Functional group in the structure of glucose is a ketone
Even though fructose is many times sweeter than other sugars why sucrose is preferred over fructose for cooking?
Answer : Once fructose has been cooked though, it loses much of its sweetness. That is why sucrose, or granulated sugar, is recommended for baking instead of crystallized fructose.
Glycosidic bond is a covalent bond formed by the condensation reaction between a sugar and the -OH group of a second compound which may or may not be the sugar.
These are of two types i.e. O- glycosidic bond (-C-0- C) and N-Glycosidic bond (-C-N-C).
Disaccharides are formed when two monosaccharide units combine by dehydration synthesis, which involves the elimination of a small molecule, such as water, from the functional groups.
Examples of Disaccharides
Examples of disaccharides are lactose (glucose + galactose), sucrose (glucose + fructose), and maltose (glucose + glucose).
Lactose (Figure 7) is the main sugar in milk and other dairy products.
It (Figure 8) is also known as ‘table sugar’. It is a common form of sugar found in sugarcane, some fruits and vegetables, and also in products, such as, cereal, ice cream, baked desserts and yoghurt.
Maltose (Figure 9) is referred to as ‘malt sugar’ and chemically consists of two glucose molecules. It is found in cereals containing barley and malt products, such as, malted milkshakes, and beer.
Lactose intolerance is a condition, in which people have digestive problems such as bloating, diarrhea, and gas after drinking milk or eating milk products (Figure 10).
Lactase deficiency and lactose malabsorption may lead to lactose intolerance. Lactose intolerance should not be confused with milk allergy.
The latter is a reaction by the body’s immune system to one or more milk proteins. An allergic reaction to milk can be life threatening.
Milk allergy most commonly occurs in the first year of the child, while lactose intolerance occurs more often during adolescence or adulthood.
Oligosaccharides contain three to ten monosaccharide units. On hydrolysis, they yield the monosaccharide units, which may be similar or dissimilar.
Trisaccharides, C18H32O16, such as, Raffinose (Figure 11), maltotriose, and stachyose (tetrasacchrides) are examples of oligosaccarides.
Polysaccharides contain more than ten monosaccharide units joined by the glycosidic bonds forming chain like structure.
The chain may be
- branched, where molecules look like branches
- unbranched, where the molecules are in a straight line
These are usually amorphous, tasteless, non-sugars and insoluble in water.
Examples of Polysaccharides
Polysacchrides can be in a structural (e.g., cellulose, hemi-cellulose, pectic substances, chitin, gum, mucilage etc.) or storage (e.g., starch, inulin, glycogen etc.) form.
Glycogen (Figure 12) is stored in the liver and muscles by humans and animals.
These are glucose polymers that are made up of amylose and amylopectin.
Cellulose (Figure 13) is an organic compound that is considered most abundant on earth and is one of the main structural constituents of plants. Wood, paper, and cotton are mostly made of cellulose.
Applications of Carbohydrates
For example, oligosaccharides are frequently linked to proteins, where they serve as markers to target proteins for transport to the cell surface or incorporate them into different subcellular organelles.
Things to Remember
- Carbohydrates provide energy to the body
- Glucose is a simple sugar that is found in many basic foods. For immediate energy, glucose is broken down during the process of cellular respiration, which produces ATP, the energy currency of the cell.
- Monosaccharides are simple sugars made up of three to seven carbons, and they can exist as a linear chain or as ring-shaped molecules.
- Disaccharides is formed when two monosaccharides held together by a covalent bond.
- Sucrose (table sugar) is the most common disaccharide, which is composed of the monomers glucose and fructose. Whereas, Fructose is made of single unit of glucose and galactose each.
- Polysaccharide is a long chain of monosaccharides linked by glycosidic bonds; the chain may be branched or unbranched and can contain many types of monosaccharides.
- Lactose intolerance is a condition, in which people have digestive problems after drinking milk or eating milk products